It might, but it's not guaranteed. In fact, not all Broncos lean due to "Bronco Lean" either.
But you never know until you start digging in and trying things. Springs sag, rear springs as well, since they can effect the front through the radius arms.
The C-bushings could be crooked/shifted, which is what you're talking about with the radius arm caps. But once shifted and locked down for any length of time, they may have taken a permanent set.
And I would not even rule out a crooked frame construction, since that has been proven to be the case many times. At least in very minor leanings anyway.
Coil spring towers welded on crooked. Coil spring cups sagged/bent/rusted over time.
Radius arm mounts welded on at different angles/heights.
That kind of stuff.
Good luck.
Paul