Because you were not having trouble before, I think we've been ignoring the possibility of the calipers hitting the knuckle. With new pads it should be back to business as usual, but with old worn pads maybe the calipers (or one of them) is touching now.
When you look down over the tires can you see plenty of daylight between the calipers and the knuckle castings? Should be at least 1/8" but more is better.
There is no logical explanation from the master cylinder effecting only one caliper of course, because it doesn't work that way. But if one side is closer to locking up than the other, then the pressure from the master would tip the scales.
There is also no logical explanation for pressure at the master cylinder, when there is no pressure on the pedal. If the pedal can still come up, and the rod is not holding the piston inward slightly, then pressure buildup is coming from another dynamic.
Perhaps a stuck piston (yes, in both masters), or the aforementioned RPCV, or the hoses as was mentioned, or perhaps even some debris in the back of the master blocking the piston from returning all the way to neutral.
We know it's in the master because loosening the master and/or loosening the hard line does release the pressure.
There's just not a "normal" reason from most experiences.
But just to rule it out, check or re-check the clearances at the calipers. Then when you're really ambitious, pull them off and check the condition of, and lubrication on, the sliding pins.
Paul