Get with your local auto paint store. Buy all of your materials from them and they will help you out. I personally like PPG, or Dupont. I've shot mostly PPG though. Stay away from cheap paint like Sherwin Williams/Martin Senor/or the crap Autozone or Summit sells unless you want to paint your rig again in 4-5 years.
Prep is 95% of a paint job, do all of your body work then prime, block sand, block sand, and then when you think your done, sand some more. After all of that clean, clean, clean, and when you think your done, clean again. Then you can shoot paint.
If your local community college has a hobby body shop, I'd suggest signing up for that, even if all you do is use the paint booth. If you need a place to work, a dedicated time, or professional help there's someone there to walk you through the process.
Good luck