Yes, that square head is the fill plug. Standard 1/2 NPT plug.
Factory spec is 50wt motor oil. Non-detergent is correct as there is no filter in the transfer case. The detergent oils are designed to keep dirt in suspension so it can be filtered out in an oil filter. Non-detergent lets it settle at the bottom of the pan. Almost impossible to find non-detergent 50wt.
The good news is normal ~90wt gear oil is the same viscosity. Motor oil and gear oil are on different scales, like Celsius and Fahrenheit. Other manufacturers that used the Dana 20 just call out for 90wt gear oil. So while 90wt isn't a match for the published spec that is 50+ years old, it is still a good oil choice. Lot s of people have been running 90wt for decades and don't even know it. When the corner service station did the full lube and changed it, not knowing any different, just filled it with gear oil and sent it on the road. There are even people who have filled it with ATF (like modern transfer cases) and not done any damage. The D20 is a very simple design that does not require specialty lubes. It will run with just about anything that is oily. I've even followed one for a day that ran no oil after punching a hole in the bottle on a rock. Finish the day, go home and put the spare one on.