Well that's interesting. Most that feel the Bilstein 5100's are not quite right for their Bronco feel they're too soft!
But either way rustbucket, going from one shock to two per wheel is not to make it ride better but more to benefit in other ways.
Of course that "better" is up to personal preference too. It will be firmer, but that might be good for some Broncos and some owners.
It should certainly corner tighter, handle big bumps better, and may end up being preferred by you. It might even ride smoother over your particular local terrain.
But one thing it won't do is ride "softer" on the road.
I've done both (but not with the Duff shocks specifically) and have both loved and hated it. It was all about the shocks and the balance of the vehicle and the conditions.
I have dual mounts on my '68 and am still going to install the mounts on my '71, but am also going to experiment with shocks. First going with dual Bilstein 5100's just to see how I like it.
Nothing wrong with trying. Other than the little bit of extra time it will take you to weld on the new mounts you have burning a hole in your garage!
Do you have the parts and shocks needed to run duals? Or are you contemplating it and still need to purchase it all?
Sounded like you already purchased the stuff, but never installed it. If it was me and I had the stuff already, I'd go ahead and install it.
Sometimes we just gotta play around. Ya know?

;D
Paul