I agree that a 19 lb cap will increase the boiling point, but I do not agree that it will help keep the engine cool. The specific heat of water at 212°F and 14.7 psi absolute, 0 psi guage is 4.2164 kJ/kg K. At 50 bar or 725 psi absolute, the specific heat is 4.205 kJ/kg K. The point of this is the specific heat capacity of an incompressible fluid, water, is bascially constanct at small pressure changes, even a very small change are very high pressure changes. With that being said, the heat removed from the engine is going to be conductive through the block, a film thickness on the walls of the water jackets, and the convection to the coolant. The conduction through the block will only change with the thickness of the material between the cylinders and the water jackets and the temperature generated in the combustion process, this is where timing and fuel mixture comes in. The film thick ness or fouling of the water jacket will reduce the amount of heat transferred to the coolant. This is due to rust, gunk, etc. The last thing is the temp and the mass flow of the coolant. If the radiator is not removing enough heat, the water temp going into the engine will be higher and the heat transfer from the engine to the coolant will be lower due to Q=mCp(Tfinal-Tinitial). The same things apply for the radiator, only the heat is going from the coolant to the copper/aluminum to the ambient air.
With that being said I have some other thoughts on high volume water pumps also. If you run a standard thermostat, but install a high volume pump, I do nto think you will see a significant change in engine cooling because the thermostat is the restrictive device in the system. Now, if you install a high flow thermostat and high flow water pump, your mass flow should increase and your effective heat transfer will increase. But at the same time, it is very important to use a thermostat. If you do not have a restriction in the system, it is possible the water will not contact all surfaces of the water jackets which will definately reduce the heat transfer.
In my opinion, the way to look at cooling is to maximize the flow rate of coolant through the engine to gain the highest amount of heat transfer. Then maximize the temperature drop in the water, pull as much heat as possible out of the coolant with the radiator. This means use a high flow water pump and thermostat and insure airflow through the radiator is fresh, not from the engine compartment, and maximized. If you still have a cooling issue after this, then you are creating too much heat for the heat exchanger area you have in your radiator and need either the largest, most efficient radiator you can fit in your bronco or need to reduce the heat generated by the engine.
I do not know what is in water wetter or other additives, but they are basically increasing the specific heat capacity of the fluid to increase heat transfer.