The valve is only one aspect of keeping two tanks. The pump setup is the other.
The electric valves "should" be capable of handling the higher pressures, but it would not hurt to verify. Syk has a good point, but they do make valves that can handle them, so finding one should not be an issue if the BC one does not work.
I have that same one made by Pollack (at least I think that's what BC used to sell) and am hoping it's good for that too.
But you will need to either be using a single external pump mounted somewhere down by the valve, have a pump in each tank, or use the aux tank as a reservoir and have a separate transfer pump to put gas into the main tank as it gets low.
I prefer in-tank pumps myself, so if you end up fitting one to the aux tank, let us know how you did it. I'm not sure I remember anyone doing that.
The aftermarket side tanks are not available from the manufacturers with in-tank pumps, but there is likely some way to do it that would work acceptably well.
But most people use the aux tank as a transfer tank I think.
Paul