Most of the parts between a 302 and a 5.0 will interchange. Essentially they're the same motor, the 5.0 is just an updated version with roller cam and lifters, plus a few other goodies.
Be aware when buying performance parts - many of them are intended to make power at high RPM's, which is basically useless to an EB, since we near redline at 5,000 RPM.
A 4 barrel, a smarter exhaust, and taking off the stupid smog junk will net you quite a few ponies. Holley and Edelbrock are great on a hot rod, but don't belong on a 4x4. Stick with a Q-jet, and save yourself a lot of headache.
There is a long standing debate on the benefit of headers, personally, I went back to manifolds and a nice quiet 2-into-1 system. I've long since outgrown the thrill of listening to a loud ass exhaust all day on the trail or the highway.