No, not possible.
It could be done, but the skills needed to do it would be that of engineering a brand new transmission and transfer case. And if you had those skills, you wouldn't be asking the question.
There is a 4-speed version of a toploader 4-speed, that does have an overdrive. It is done by making it a 3-speed, flipping the linkage on the 3-4 shift. So the direct drive is now 3rd gear (instead of 4th) and what was 3rd gear is now setup as an overdrive 4th gear. And the ratio for 2nd gear is changed to make the spacing correct. 70's Ford engineering taking what they had and re-working it into an overdrive transmission without too much work. I recall the Econoline version is the better one, has a bearing for overdrive instead of a bushing used in cars.
At this point they are a bit difficult to find. Find a 40+ year old transmission that is usable, or for that matter even rebuildable. And you would need that exact transmission case as it has a bulge in the case to fit the larger overdrive gear.
Realistically, there are plenty of better 5-speed options that are way more available.
Now the other question, can you even take an overdrive? What axle gears do you have now? What size tire? Even what engine? Good chance you don't have enough gearing to use an overdrive. Are you thinking you need an overdrive based on engine sound?