Hmm, can't say I've seen that before. They do get tight sometimes, held in by years of burned-on oil sticking it to the rubber grommet, but not sure that's the only thing at work here.
Any chance you can see if it's been glued in by something? Does it have the standard looking rubber grommet in the valve cover that the PCV is inserted in to? Might just be that the grommet has swelled, and then hardened. I'm guessing if you pull hard enough it will come out, but it might also break the grommet into pieces.
Can you tell if the rubber is still soft, or if it has turned rock hard resembling resin?
You could start the process by spraying it down with various chemicals. Carb cleaner comes to mind first, to dissolve the oil buildup if that's what's holding it. Maybe other stuff too, but not sure until we know more.
The good news is that both the valve and the grommet are available new, but you would want to know the valve cover and grommet are original. If not sure, we might be able to help if we can see it.
If you can take a pic that would be great. If you do not want to become a contributor yet, you can put images in your "Garage" and "Gallery" locations. Or use another online hosting site you might already use and link the location to this discussion.
If you're going to be doing a lot of image posting coming up though, the 12 bucks a year to be a contributor is well worth it.
good luck. Look forward to seeing this valve setup.
Oh, and what year is the Bronco? What engine?
Paul